Compounds containing one or more azo groups nn linked to two carbon atoms have a variety of uses. Further work on transformation of the cobaltii complex of 2. Density functional study cavus ms 1, gur m 2, vurdu cd 1, kocaokutgen h 4, sayiner g 3 and kandemirli f 1. The study indicated that the type of lateral groups and their position adversely. In the following, we have summarized some recent syntheses of azo dyes and. Synthesis of azo compounds organic chemistry portal. Developing a method for the analysis of azo dyes using the. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated gently, then water 10 ml was added in order to dissolve the solid. Compounds 183 are convenient photochemical azo precursors. Applying different extraction procedures and different analytical technologies toxicological assessment. Mostly, synthesis of azo compounds involves diazotization of substituted primary. Potential for use as sonodynamic sensitizers for cell killing.
Azo group is stabilised by becoming part of extended delocalised. Pdf new directions in the chemistry of azocompounds. But in our study, all the spectral data show that 2substituted phenyl azo 4,6. On the chargetransfer excitations in azobenzene maleimide. Synthesis, characterization of new azo compounds and their. Aryl azo compounds are usually stable, crystalline species. The two compounds, which can be viewed as being composed. Irradiation at 254 nm photochemically cleaves the ring and the resulting azo compounds often absorb little at these wavelengths and the. Study on the reactions of azo compounds with acyl halides.
In general azo resorcinol compounds can exist in azo hydrazone tautomeric forms. New directions in the chemistry of azocompounds research. The environmental, health and economic impacts of textile. Synthesis and identification symmetrically azo dyes. Journal of chemical and pharmaceutical research, 2016, 85. Gromova, practical manual of spectrophotometry and. The most important contribution of azo compounds to radical chemistry is in their role as reaction initiators. Variation in molecular stacking resulting from the different polarity of liquid crystalline molecules. Gaskelld, xiulin fana, ji chena, tao denga, ruixing. A number of studies have shown that, in aqueous media, many azodyes, and. Classifications, properties, recent synthesis and applications of azo. It exists mainly as the trans isomer, but upon illumination. Photoswitchable systems with chargetransfer ct transitions have gained much attention during the recent years because of their many emerging applications.
Our interest in this molecule stems from its ability to act as a diamine. Where r and r are arene groups more stable than alkyl groups. Biological studies of syntheised azo compounds of indole. The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5quinolinesulfonic acid, while the diazol components were sulfanilamide and a number of its derivatives. As well as the study was achieved through the complexes formed between these a new prepared symmetrically azo dyes. Study the electrical conductivity for a new azo compound. Combinatorial synthesis of azo dyes linfield college. General procedure for the synthesis of amides from azo compounds by smticl 4. They are a commercially important family of azo compounds, i. Synthesis of some azo compounds and a study of their properties.
Defining threshold levels for the extracted compounds compliance. Antioxidant activity study hala s alatbi, bushra k alsalami and iqbal j alassadi university of basrah,college of science, department of chemistry,basrahiraq. Novel compounds 222hydroxy4nitrophenyl hydrazono1,3diphenyl propane1,3dione and 222hydroxy4nitrophenyl hydrazono1phenyl butane1,3dione are prepared on the. Synthesis, spectroscopic, thermodynamics and kinetics.
Photochemical and electronic properties of conjugated bis. However, such compounds are seldom used as polymerization initiators and further discussion on this subject is beyond the scope of this chapter. A detailed theoretical uv study of some azo acrylate compounds. Preparation of azo compounds for the study of inhibition.
Azo compounds as a family of organic electrode materials. When the reactivity of the aryl group is increased by the presence of electron donor substituents or fused rings, the direct cn bond formation leads to. Azo dyes represent the largest production volume of dye chemistry. Azo dyes are extremely important in variety of industries for variety of technical purposes. Epr spin trapping study of the decomposition of azo compounds in aqueous solutions by ultrasound. Under nitrogen atmosphere, 1 mmol of azo compound 1 dissolved in dry thf 1 ml was added to the solution. Azo dyes represent vital components to the fabrics and textiles industries, and diazonium salts are the building blocks that these compounds are made from.
Reduction azides are reduced to tinsubstituted amines by. Azo dyes are organic compounds bearing the functional group r. Azo compounds as a family of organic electrode materials for alkaliion batteries chao luoa, oleg borodinb, xiao jia,c, singyuk houa, karen j. The atomic groups attached to the nitrogen atoms may be of any organic. Synthesis and characterization of azo compounds and study. Azo compound, any organic chemical compound in which the azo group. Biodegradation of azo dye compounds premier publishers.
They are compound bearing the functional group rnnr in which r and r can be either alkyl or aryl groups. Studies on synthesis and spectral characterization of some. Some of the azo compounds are studied as hiv inhibitors of viral replications25. The study indicated that the type of lateral groups and their position adversely affects the mesomorphic properties of these compounds. The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5. Variation in molecular stacking resulting from the. Biodegradation of azo dye compounds kamlesh shah department of biotechnology, p. New azo mesogenic compounds with oh, ch 3, cl, and f side groups on the central benzene nucleus were synthesized. Azo compounds are very important molecules and have attracted much attention in both academic and applied research 1520.
The nature of the aromatic substituents on both sides of the azo group controls the colours of the azo compounds as well as. Study of removal techniques for azo dyes by biosorption. A detailed theoretical uv study of some azoacrylate. Synthesis, azo compounds, guanine and, biological activity, bacteria introduction azo ligands of heterocyclic. Epr spin trapping study of the decomposition of azo. Likewise, several case studies have linked azo pigments with basal cell carcinoma. Hence, a series of naphtholic azo dyes 19 were synthesized via diazotization of substituted aniline. Azobenzene is the prototypical aromatic azo compound. Synthesis of most azo compounds involves diazotization of a primary aromatic amine. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated. Asian journal of research in chemistry and pharmaceutical. Most common method variables are column chemistry stationary phase. A study of the inhibition of tumor growth in mice and rats with azo compounds. Synthesis and characterization of azo compounds and study of the.
A green dehydrogenation of hydrazo compounds using basic alumina or kfalumina under solventfree conditions afforded azo compounds in good to excellent yields. We have investigated the photophysical, photochemical and electrochemical properties of two bis azo derivatives, e,e. Pdf on aug 1, 2011, omer rasheed published new directions in the chemistry of azocompounds find, read and cite all the research you. The unit containing the nitrogennitrogen double bond is called an azo group. Azo compounds are compounds bearing the functional group diazenyl r. Azo dyes are class of compounds containing a nn double bond generally connected to aromatic ring, due to their ability to absorb visible light and ease of. Synthesis of some azo compounds and a study of their. Reduction azides are reduced to tinsubstituted amines by reaction with tin hydrides.
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